Naphtha
The light petroleum fraction that is the backbone of petrochemical production — cracked into ethylene and propylene to make plastics, and reformed to boost petrol octane.
Definition
Naphtha is a light petroleum fraction with a boiling range of approximately 30–200°C (86–392°F), produced during crude oil distillation between liquefied petroleum gas (LPG) and kerosene/jet fuel in the atmospheric distillation column. It is a colourless to pale-yellow flammable liquid with a characteristic petroleum odour.
Naphtha is broadly divided into two grades:
- Light naphtha (LN): Boiling range ~30–90°C; used primarily in petrol blending and as a feedstock for isomerisation units (to improve octane)
- Heavy naphtha (HN): Boiling range ~90–200°C; the primary feedstock for catalytic reformers (producing reformate for petrol blending) and for steam crackers (producing ethylene and propylene)
Naphtha in the refinery product slate
| Refinery stream | Boiling range | Density | Primary uses |
|---|---|---|---|
| LPG (propane/butane) | <30°C | ~0.50 kg/l | Heating, cooking, autogas. See LPG entry |
| Light naphtha | 30–90°C | ~0.65 kg/l | Petrol blending; isomerisation feedstock |
| Heavy naphtha | 90–200°C | ~0.72 kg/l | Steam cracking; catalytic reforming feedstock |
| Kerosene / jet fuel | 150–250°C | ~0.80 kg/l | Aviation turbine fuel; heating |
| Diesel / gasoil | 200–360°C | ~0.83 kg/l | Road transport; heating. See gasoil entry |
| Vacuum gasoil (VGO) | 350–560°C | ~0.90 kg/l | FCC/hydrocracker feedstock; produces diesel/gasoline |
| Heavy fuel oil | >560°C | ~0.96 kg/l | Marine bunkers; power generation. See HFO entry |
Naphtha as petrochemical feedstock
The largest use of naphtha globally is as a steam cracker feedstock to produce ethylene, propylene, and other light olefins and aromatics. The process:
- Naphtha is mixed with steam (to dilute hydrocarbons and reduce coke formation) and fed into a cracking furnace
- At ~800–850°C with a residence time under 1 second, molecular bonds break (crack) to form smaller molecules
- The cracked gas is rapidly quenched to 300°C within milliseconds to prevent the products from reacting further
- Products are separated by compression and fractionation into: ethylene (~30%), propylene (~15%), butadiene (~4%), benzene, toluene, xylene (BTX aromatics), and pyrolysis gasoline
| Product from naphtha cracking | Approximate yield | Downstream uses |
|---|---|---|
| Ethylene (C₂H₄) | ~28–32% | Polyethylene (PE), PVC, polystyrene, ethylene glycol (antifreeze, polyester) |
| Propylene (C₃H₆) | ~14–16% | Polypropylene (PP), acrylonitrile, propylene oxide |
| Butadiene (C₄H₆) | ~4–5% | Synthetic rubber (SBR, polybutadiene) |
| Benzene / Toluene / Xylene | ~10–15% | Styrene, PET plastics, solvents, paints |
| Pyrolysis gasoline | ~10–15% | Blended into petrol; aromatic extraction |
| Methane / hydrogen fuel gas | ~15–20% | Burned as cracker fuel |
Ethylene is the world's most-produced organic chemical by volume — the foundation of the plastics and synthetic materials economy. A naphtha steam cracker producing 1 million tonnes/year of ethylene requires approximately 3–3.5 million tonnes of naphtha feedstock annually.
Naphtha vs ethane: the feedstock competition
In the United States, the shale gas revolution fundamentally shifted cracker feedstock economics. Natural gas liquids (NGLs), particularly ethane, are significantly cheaper than naphtha as a cracker feedstock and produce higher ethylene yields:
| Feedstock | Ethylene yield | Cost basis (2026) | Geography |
|---|---|---|---|
| Ethane (NGL) | ~80% ethylene yield | Very low cost; tied to gas prices | US (Gulf Coast), Middle East |
| Propane/butane (NGL) | ~50–60% ethylene | Moderate; LPG-linked price | Middle East, Asia |
| Naphtha | ~28–32% ethylene | Higher; crude oil-linked price | Europe, Northeast Asia (Japan, Korea, Taiwan) |
US and Middle Eastern crackers primarily use cheap ethane, giving them a significant cost advantage over European and Asian naphtha-based crackers. This cost disadvantage has driven European cracker rationalisation — several European ethylene plants have closed in recent years. The naphtha-ethane spread determines the competitiveness of European and Asian petrochemical producers.
For the LPG market context, see our LPG glossary entry. For natural gas and LNG pricing, see our LNG glossary entry. For crude oil pricing that underpins naphtha costs, see our Brent crude entry.
Naphtha pricing
Naphtha is priced in US dollars per metric tonne. Key benchmarks:
- CIF NWE naphtha: Cost, insurance, freight to Northwest Europe — the European benchmark, published by Platts (S&P Global) and Argus
- CFR Japan naphtha: The Asian benchmark, closely watched because Japan and South Korea are the largest naphtha cracking markets
- MOPJ (Mean of Platts Japan): The average of the month's daily Platts Japan naphtha assessments — used in long-term supply contracts in Asia
Naphtha typically trades at a discount to crude oil on an energy equivalent basis (naphtha crack is negative or at a small premium). The spread between crude and naphtha reflects refinery processing economics and the balance between supply (refinery yields) and cracker/blender demand. In periods of strong petrochemical demand, the naphtha crack tightens; in downturns, it weakens.
What is naphtha and what is petroleum naphtha used for?
Naphtha — specifically petroleum naphtha — is the lightest liquid fraction from crude oil distillation, with a boiling range of approximately 30-200 degrees C. It sits between LPG and kerosene in the refinery distillation column. Petroleum naphtha has two primary uses: as the dominant feedstock for steam crackers in Europe and Asia (where it is thermally cracked at 800-850 degrees C to produce ethylene and propylene — the building blocks of plastics), and as a petrol blending component (light naphtha, after catalytic reforming, boosts octane in the finished fuel). The U.S. EIA Weekly Petroleum Status Report tracks naphtha as part of the broader petroleum product slate, and the IEA's oil product analysis covers global naphtha demand trends.
Naphtha prices are highly correlated with crude oil but trade at a discount on an energy-equivalent basis. The naphtha-crude spread (or "naphtha crack") reflects the balance between refinery supply and demand from petrochemical crackers. When cracker demand is strong and plastics margins are healthy, naphtha prices firm relative to crude. The OPEC Annual Statistical Bulletin provides data on naphtha production by region, and the European Commission's weekly oil bulletin includes naphtha pricing alongside other refined products.
Frequently asked questions
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What is naphtha and what is it used for?
- Naphtha is a light petroleum fraction (boiling range ~30–200°C) produced from crude oil distillation. Its two main uses are: (1) Petrochemical feedstock — steam cracked at 800–850°C to produce ethylene (~30% yield) and propylene (~15%), the building blocks of plastics; and (2) Petrol blending component — reformed naphtha (reformate) boosts octane in petrol. Naphtha is the primary ethylene feedstock in Europe and Asia.
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What is steam cracking and how does naphtha become ethylene?
- Steam cracking heats naphtha mixed with steam to ~800–850°C in a furnace for under one second, breaking long-chain molecules into short-chain olefins: ethylene (~30%), propylene (~15%), butadiene (~4%), and aromatics. The cracked gas is immediately quenched and separated by distillation. Ethylene is the world's most-produced organic chemical and the precursor to polyethylene, PVC, polystyrene, and most plastics.
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How does naphtha price relate to crude oil and petrol prices?
- Naphtha prices are closely correlated with crude oil, typically trading at a small discount to crude on an energy-equivalent basis. The naphtha crack spread (naphtha price minus crude) reflects cracker demand versus refinery supply. Strong petrochemical demand tightens the crack; economic downturns weaken it. Naphtha does not directly drive petrol pump prices (diesel crack spread is more relevant) but feeds into plastics and polymer prices throughout the economy.